Heavy Oil Residue Upgrading With Iron Based Catalysts Under High Hydrogen Pressure

نویسندگان

چکیده

In this study, effective and easily accessible cheap catalysts that assist converting heavy oil residue to lighter products with high yield are investigated. Hydrocracking experiments were carried out in a 10 ml stainless steel bomb-type reactor up down stirrer at 200 times of reciprocation per minute. The catalyst mixture provided the minimum coke was FeSO4.H2O, binary mixtures FeSO4.H2O metal oxides (Fe2O3, Al2O3, CaO, SiO2) Fe2O3, Al2O3 SiO2 elementary sulphur used as catalyst. Experiments conducted 425 0C for 90 minutes initial pressure 100 bar H2. amount coke, liquid C5- gas calculated each experiment. Gel Permeation Chromatography (GPC), Nuclear Magnetic Resonance (1H NMR) elemental analysis Iranian residue. Differential Scanning Calorimeter (DSC) analyze According results, is achieved by FeSO4.H2O+SiO2 Although FeSO4.H2O+SiO2, middle distillate containing toluene soluble fraction (TSF) maximized Fe2O3+Al2O3+Sulphur mixture. addition, product selectivity reactions least formation showed direction light products, not formation.

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ژورنال

عنوان ژورنال: Journal of Advanced Research in Natural and Applied Sciences

سال: 2021

ISSN: ['2757-5195']

DOI: https://doi.org/10.28979/jarnas.979667